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LOI andUL-94V Test for Cured Epoxy Resins
The flame-retardant properties of cured epoxy resins were examined by measuring the LOI. To demonstrate the flame-retardant properties of DOPO epoxy resin, DOPO epoxy, and Bis-A epoxy were cured with (1) Ph Nov, (2) DDS, and (3) DICY for comparison. The LOI values are shown in Table III. Increased char formation can limit the production of combustible carbon-containing gases, decrease the exothermicity due to pyrolysis reactions, as well as decrease the thermal conductivity of the surface of a burning material.24 DOPO epoxy cured with Ph Nov, DDS, and DICY had LOI values of 34, 32, and 36 that were higher than those of Bis-A epoxy cured with Ph Nov, DDS, and DICY (LOI 5 26, 22, 21). The UL- 94Vtest determines the upward-burning characteristics of a solid. Five sample bars of each cured epoxy resins suspended vertically over surgical cotton were ignited by a Bunsen burner; two ignitions of 10 s each were applied to the sample. The results of UL-94V and LOI test are listed in Table III. DOPO epoxy resin, besides being superior to phosphorus-free epoxy resin in flame retardancy, also generated much less visible smoke than phosphorus-free epoxy resin.
Dynamic Viscoelastic and Thermal Properties of Flame-Retardant Epoxy Encapsulants
Owing to excellent heat, solvent and chemicalresistance, good adhesion and inexpensiveness, epoxy resin has been widely employed in the encapsulation of microelectronic devices. In this study, DOPO epoxy and TBBA epoxy (tetrabromobisphenol A epoxy resin) were compared for their flame retardancy in the encapsulation formulation . Bis-A epoxy was blended with various amount of DOPO epoxy and then cured with Ph Nov to give the cured products with phosphorus content of 0, 0.58, 1.03, and 1.45% (Bis-A/Ph Nov, DOPO-A, DOPO-B, DOPO-C). In the same manner, Bis-A epoxy was blended with TBBA epoxy and then cured with Ph Nov to give the cured products with bromine content of 4.01, 7.24, and 9.91% (TBBA-A, TBBA-B, TBBA-C). Thermal properties of cured epoxy resins are shown in Table IV. It should be noted that Tg of cured epoxy resins increased with the increase in phosphorus content while Tg decreased with the increase in bromine content . The result may be attributed to the bulky rigid phosphorus-containing group.

LoiAndul-94v测试环氧树脂好 火焰-环氧树脂阻燃性能好,是衡量一家研究. 显示火燃烧特性dopo环氧树脂、环氧树脂dopo,国际清算银行的一架被治好了(1)与电酸碱、国内发展服务(二)、(三)、dicy比较. 意向书值见表三. 增加烧焦形成可以限制生产易燃碳含有气体,减少exothermicity由于热反应,以及降低导热水面一烧material.24dopo环氧树脂治愈与酸碱度11月,国内发展服务、Dicy已Loi价值34、32、36所高于国际清算银行-环氧树脂治愈与酸碱度11月,国内发展服务, Dicy和(526跟,22、21). 该运动的决定94vtest向上烧了坚实的特点. 酒吧每五个样本纵向比手术治愈环氧树脂暂停棉点燃了本生灯; 中国汽车102适用于每个人的样本. 结果证明,94V,测试指令表列第三. dopo环氧树脂,除了向上级磷无以环氧树脂retardancy火焰,也带来更明显磷烟比无环氧树脂. viscoelastic动态特性和热火阻燃环氧树脂encapsulants 由于出色的热、溶剂和chemicalresistance、善意与廉、环氧树脂已广泛应用于微电子封装的装置. 在这项研究中,索dopoTbba而成,(一Tetrabromobisphenol环氧树脂),比较他们的火焰retardancy概括提法. 国际清算银行-环氧树脂是结合不同数量索dopo然后以治愈酸碱电给治好的产品磷含量0、0.58、1.03、1.45%(11月Bis-a/ph,DopoA、DopoBDopo-C). 以同样的方式,国际清算银行的结合是一个绕绕,然后Tbba治愈与酸碱电给治好溴化物产品内容4.01、7.24、9.91%(TBBAA、TBBABTBBA-C). 热性能好环氧树脂见表四. 应该指出的TG增加治愈环氧树脂增加磷的含量的增加而减少TG溴含量. 结果可能是由于大量的硬性磷载组.

他说的很对